Engineer & Medical

Chemical Equilibrium question bank (Chemistry)

Practice 734 free Engineer & Medical Chemistry - Chemical Equilibrium questions with answers and step-by-step solutions.

Q1.

Consider the following gaseous equilibrium in a closed container of volume ' V ' at $\mathrm{T}(\mathrm{K})$.
$\mathrm{P}_{2}(\mathrm{~g})+\mathrm{Q}_{2}(\mathrm{~g}) \rightleftharpoons 2 \mathrm{PQ}(\mathrm{g})$
2 moles each of $\mathrm{P}_{2}(\mathrm{~g}), \mathrm{Q}_{2}(\mathrm{~g})$ and $\mathrm{PQ}(\mathrm{g})$ are present at equilibrium. Now one mole each of ' $\mathrm{P}_{2}$ ' and ' $\mathrm{Q}_{2}$ ' are added to the equilibrium keeping the temperature at $\mathrm{T}(\mathrm{K})$. The number of moles of $P_{2}, Q_{2}$ and $P Q$ at the new equilibrium, respectively, are

(A)
$1.66,1.66,1.66$
(B)
$2.56,1.62,2.24$
(C)
$2.67,2.67,2.67$
(D)
$1.21,2.24,1.56$
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Q2.

For the following gas phase equilibrium reaction at constant temperature,
$\mathrm{NH}_{3}(\mathrm{~g}) \rightleftharpoons 1 / 2 \mathrm{~N}_{2}(\mathrm{~g})+3 / 2 \mathrm{H}_{2}(\mathrm{~g})$
if the total pressure is $\sqrt{3} \mathrm{~atm}$ and the pressure equilibrium constant $\left(\mathrm{K}_{\mathrm{p}}\right)$ is 9 atm, then the degree of dissociation is given as $\left(x \times 10^{-2}\right)^{-1 / 2}$. The value of $x$ is $\_\_\_\_$. (nearest integer)

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